Том 8, №1, 2016
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НАНОСИСТЕМЫ



МЕМБРАННЫЕ МОДЕЛИ И АНЗАЦ ДВУХСЛОЙНОГО ГРАФЕНА КАК МЕМБРАНОМИМЕТИКА
Градов О. В.
Институт энергетических проблем химической физики им. В.Л. Тальрозе, Российская академия наук, http://www.inepcp.ru
119334 Москва, Российская Федерация
gradov@chph.ras.ru

Поступила в редакцию 16.06.2016


Аннотация. Начиная с пионерских работ основателя мембраномиметической химии (“membrane mimetic chemistry”) Яноша Фендлера, известно, что некоторые атомные или молекулярные (в том числе наноразмерные) кластеры и пленки способны имитировать функции мембран. Мембраномиметиками могут быть как частично упорядоченные среды (“soft matter”), так и твердофазные носители, в том числе – в иммобилизованном состоянии. Известно, что мембраномиметические характеристики могут обнаруживать как пленочные проводники, в том числе – обладающие магнитными свойствами, так и полупроводники. Если представить агентный обмен на мембранах в операторном виде, то химизм мембран или их миметиков, равно как различие между атомными и молекулярными кластерами или же слоями, перестают иметь значение, вследствие чего мембраномиметика мезоструктур и наноструктур существенно не отличаются друг от друга в агентном приближении. Данный обзор рассматривает различные аспекты подобия свойств графеновых наноструктур свойствам мембран и бионических мембраноподобных наноматериалов.

Ключевые слова: графен, двухслойный графен, бислои, мембраномиметика, нанобионика

УДК 544.77, 53.098

Библиография – 112 ссылок

РЭНСИТ, 2016, 8(1):25-38 DOI: 10.17725/rensit.2016.08.025
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